Hi Ludwig,
Unfortunately at the moment, FePEST graphical interface does not support unsaturated parameters as a Parameter Definition for calibration.
However, you can still calibrate these variables including a so-called IFM-implemented parameter definition. You will need to write an IFM plug-in to retrieve and set unsaturated parameters, basically you will use the following functions:
IfmGetMatUnsatAirEntryPressureHead
IfmGetMatUnsatFittingCoefficient
and their corresponding IfmSet... functions.
Cheers,
Carlos