The parameter f_X_Out in the ADM1 model is used to retain the sludge in the digester, i.e. to mimic the behaviour that more solids are retained within the digester than the soluble fractions.
If you set f_X_Out to 1, then the quantity of solids and solubles are percentage wise the same. When you set f_X_Out to zero than all solids are retained within the system.
Ideally you should compare your effluent values with the values that you get from your simulations. You can also try to match the (wanted) sludge retention time in the digester.