I'd typically do an isosurface for a pressure of 0 (or close to 0) in a 3D view to determine the water table location visually. The hydraulic head in slice 1 approximately is the water table elevation, but not exactly. In case that groundwater recharge is applied, this has to be passed down to the water level, which will result in slightly higher hydraulic head in slice 1 than at the water table.